Technology
About Choetsu Technology®

Introduction

'Choetsu Technology®' is expected to deeply involve advancements in many fields, including materials science and medicine,
contributing to global themes such as plastic reduction and SDGs, and further to the virtuous cycle of economy and environment,
as a safe, cutting-edge technology originating from Japan.

What is Choetsu Technology®?

'Choetsu Technology®' is a unique silica coating technology invented in 1997 and still under research,
originating from Japan. It generates a glassy thin film by reacting with OH groups (moisture or humidity) in the air or within substances,
without requiring strong acids, under near room temperature and pressure conditions.
It is chemically neutral and does not contain harmful substances, naturally decomposing in the environment after disposal,
thus imposing no burden on the human body or the environment.

*Choetsu Technology is a registered trademark of Choetsu Kaken Co., Ltd.

Features of Choetsu Liquid

[Usage]

Apply Choetsu Liquid to paper, wood, stone, resin, metal, etc.,
generating a glassy thin film on the surface or inside the substrate through chemical reaction bonding.

[Power and Effect]

Enhances the inherent water repellency, oil repellency, and rigidity of glass, and can impart heat resistance, flame retardancy, insulation, transparency,
radiation shielding, and antibacterial properties (adsorption and decomposition).
Since application is done at room temperature in liquid form, it can be applied evenly without damaging the material.
It is chemically neutral and generates a safe film layer for both objects and the human body in three-dimensional directions.

The liquid is essentially colorless and transparent. Its viscosity is generally 0.002 to 0.016 Pa.s, offering excellent workability.
The liquid is not of a single type; it is possible to adjust the film layer according to functional requirements.
It can accommodate hardness, flexibility, moldability, and barrier properties.
It generates chemical bonding reactions with the substrate fibers in three-dimensional directions without requiring large amounts of water or strong acids at room temperature and pressure.
(The reaction is generally accelerated by heating.)

Applications of Choetsu Liquid

Choetsu Liquid provides the following functions:

- Environmentally Friendly

This technology generates a glassy thin film through reactions without requiring large amounts of water or strong acids, at near room temperature and pressure. It is chemically neutral and free of petroleum-based resins, making it a safe technology that does not burden the human body or the natural environment.
Additionally, upon combustion decomposition, it returns to silicon, avoiding environmental pollution. It can be disposed of as general household waste.

① Safe for the Human Body

Since the liquid contains no petroleum-based resins, it is safe for the human body. A coated spoon has obtained a report compliant with US FDA (Food and Drug Administration) standards and passed EU food contact tests, confirming the safety of Silicagen Coat.

② Water Repellent

Imparts strong water repellency without compromising the substrate's texture. When applied to paper, it helps maintain shape even during prolonged water immersion.

③ Oil Repellent

Prevents the penetration of oils with small molecules and low intermolecular density, such as olive oil.

④ Antifouling and Antibacterial

Titanium compounds are uniformly dispersed within the amorphous structure formed by the bonding reaction, performing adsorption and decomposition. This exhibits antifouling and antibacterial effects similar to photocatalysts, with effects lasting gently over a long period. It is characterized by exhibiting certain effects even in dark places.

⑤ Flame Retardant

Materials such as wood and paper treated with Choetsu Technology® are covered with a glassy thin film, making them less likely to combine with oxygen and thus less flammable.

⑥ Weather Resistance

The liquid seals microscopic cracks and irregularities invisible to the naked eye in three dimensions. For wood, it prevents water infiltration, discoloration/fading from UV rays, and general deterioration.

⑦ Strength Enhancement

When applied to wood, it improves surface hardness. When applied to substrates with fibers like paper or cloth, the glass film coats the fibers, enhancing tensile strength.

Examples of Technology Application

Function

Safe for
the Human Body

Water Repellent

Oil Repellent

Antifouling
Antibacterial

Flame Retardant

UV Resistance
Weather Resistance

Strength Enhancement

Barrier Property

*Depending on the material to be applied, it may not be applicable.

⑨ Radiation Shielding

Choetsu Technology is also advancing research to mitigate the effects of radiation on the Earth and human body, succeeding in evenly dispersing tungsten molecules in the liquid.
We have developed materials with radiation shielding properties that surpass lead by coating fibers such as paper, and currently hold multiple related patents and utility models.

<Mechanism>

Fine tungsten powder binds with Silicagen Coat and siloxane through the oxide film on the surface.
When Silicagen Coat combined with tungsten is applied and penetrated into paper or fibers, tungsten powder is uniformly dispersed on the coated surface.

<Production and Performance of Radiation Shielding Fabric>
Our company has developed radiation shielding fabric using our unique radiation shielding technology.
The tungsten-coated radiation shielding fabric uses polyester as the base material.
The fabric contains tungsten 740g/m² (87.5% by weight), polyester 85g/m², and glass thin film 105g/m².

Optical microscope observation of the outer surface and cut surface of tungsten-coated radiation shielding fabric.
Both figures show that the tungsten powder is covered with a chemically bonded glass thin film and is uniformly and stably embedded in the fabric.

<Features of Our Radiation Shielding Clothing>

1)
High radiation shielding performance

2)
Excellent strength, waterproof and water-repellent properties, while maintaining excellent flexibility
3)
Lightweight, making it easy to transport
4)
Can be cut to size according to the application and sewn with a sewing machine
5)
Can be easily bent by hand
6)
The tungsten at the cut surface is incorporated in a chemically stable form called siloxane bonding within the glassy material and is not exposed on the surface
7)
Lead-free and a safe material certified by the US FDA, which oversees food and drugs

<Examples of Productization of Our Radiation Shielding Fabric>
① We delivered radiation shielding fabric mixed with tungsten to companies developing radiation shielding clothing.

Image8-7

② As auxiliary shielding for high-energy accelerators, we produced and delivered collimator covers.

Purpose:
Shielding around equipment for secondary gamma rays during high-energy accelerator operation

Developed Product:
Shielding of decay gamma rays from activated equipment and shielding bodies during maintenance and inspection, requiring detachability and adhesion to key points of the accelerator
Material:
Flat shielding fabric coated with tungsten powder

<Reference>
Shielding performance against 150keV X-rays and thermal neutrons
The shielding performance of tungsten shielding fabric was measured using an imaging device at the Kyoto University Research Reactor Institute (KURNS). The radiation sources were 150 keV X-rays from the TRIX-150WE-OC X-ray generator and thermal neutrons from the E-2 hole of the KUR reactor. Transmission imaging of X-rays and neutrons through crepe-processed fabric and flat fabric was captured using a combination of a scintillator and a CCD camera.
The results are as follows.

The two figures on the left in the diagram show the X-ray transmission results, and the right shows the thermal neutron results. Both the X-ray and neutron transmission images of the flat fabric on the right show no shading, indicating that tungsten was uniformly applied. The numbers represent the transmission ratio of radiation through the entire fabric. Subtracting the transmission ratio from 1 gives the shielding ratio of the fabric.

The above shows the shielding performance of tungsten shielding fabric in terms of shielding rate, etc.
The shielding rate is quite high at 46.8% for the flat fabric. On the other hand, the crepe-processed fabric has a shielding rate of 59.4%, and considering that the weight of the fabric is almost twice that of the flat fabric, it can be said that it is not as high as the weight ratio. Especially when considering the exponential attenuation of radiation within the shielding body, the attenuation trend for the flat fabric extended to the weight of the crepe-processed fabric and evaluated with a transmission ratio of 0.26 calculated shielding rate of 74% is even lower.
The shielding performance of each shielding fabric is equivalent to a lead thickness of 0.264mm for the flat fabric and 0.377mm for the crepe-processed fabric. Compared to lead of the same weight, the shielding performance is three times for the flat fabric and about twice for the crepe-processed fabric.
Additionally, the transmission rate of thermal neutrons was 98.9% for the flat fabric and 98.0% for the crepe-processed fabric. As a result, the neutron shielding rate was 1.1% and 2.0%, respectively, and it was found to be almost proportional to the weight of the fabric.

Comparison with Similar and Competing Technologies

Choetsu Technology belongs to a high rank overall as a shielding for scattered gamma rays and X-rays.

For inquiries about original development liquids, please contact us through the inquiry form

Research Examples of Choetsu Technology®

◇ It has been confirmed that polyester fabric (cloth) coated with Silicagen Coat
has water repellency exceeding that of fluorine-based water repellents.

As a result of conducting water repellency function tests by applying the same amount of Silicagen Coat and fluorine-based water repellent to 100% polyester, 100% nylon, and 100% cotton fabrics in-house, it was confirmed that polyester has water repellency exceeding that of fluorine-based water repellents, and nylon also has the same level of water repellency (grade 4) as polyester.
Amid concerns about the harmfulness of fluorine-based water repellents, the demand for Silicagen Coat as a safe water repellent that does not contain any fluorine is expected. (Testing organization: Japan Textile Products Quality and Technology Center)

Details herepdf


◇ A spoon coated with Silicagen Coat passed the food contact test,
confirming the safety of Silicagen Coat.

In the EU, where disposable plastics are banned, a wooden cutlery coated with our Silicagen Coat, which is attracting attention as an alternative, passed the food contact test, confirming the safety of Silicagen Coat. Early practical application of wooden cutlery in the EU is expected. (Testing organization: BUREAU VERITAS)

Details herepdf


◇ By applying Choetsu Technology®, we succeeded in smoothing the surface of removable dentures used in the dental field
and effectively making them antibacterial.

By applying silica resin coating technology (Choetsu Technology®), we succeeded in smoothing the surface of removable dentures used in the dental field and effectively making them antibacterial. A joint research group from Tsurumi University, Neutron Science Center of the Comprehensive Research Organization, and the Institute for Solid State Physics at the University of Tokyo succeeded in effectively carrying hinokitiol, which has antibacterial activity, on the surface of dentures using silica resin coating technology (Choetsu Technology®), and using CFU assay, fluorescence microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, etc., it was revealed that the application of silica resin coating technology (Choetsu Technology®) can effectively reduce surface roughness, improve hydrophobicity, and effectively suppress the growth of the fungus Candida albicans, which causes denture stomatitis. The paper also mentions the potential application of silica resin coating technology (Choetsu Technology®) to various medical materials, and it is planned to proceed with research for clinical application in the future.
The details of this research result were published in the electronic version of Clinical Oral Investigation on August 15, 2022 (https://doi.org/10.1007/s00784-022-04670-z).

Details herepdf


◇ Silicagen Coating: A High-Performance Protective Film with Antifouling and Antibacterial Effects

The University of Tokyo and
Neutron Science Center of the Comprehensive Research Organization (CROSS)

  • In the environmentally friendly "Silicagen Coating" that gives paper water resistance and moderate strength, it was discovered that titanium oxide nanoparticles are spontaneously formed, exhibiting mild and sustained photocatalytic effects.
  • The coating film is strongly fixed to the substrate surface, and it was confirmed that the substrate is protected for a long period by excellent antifouling and antibacterial effects due to the photocatalytic effect.
  • Silicagen Coating not only serves as a substitute for plastic for paper but also works as an excellent high-performance protective film by applying it to materials such as glass, ceramics, and plastics, greatly expanding the possibilities of materials.

  • The press release from the Institute for Solid State Physics at the University of Tokyo is here.
    This achievement was published in the May 13 issue of Industrial & Engineering Chemistry Research, published by the American Chemical Society.

Details herepdf


◇ Application of Silicagen Coating to Cultural Properties

Efforts are beginning to utilize the effects of Choetsu Technology, such as water repellency, antifouling, and antibacterial properties,
to maintain and preserve cultural properties in their natural form and prevent weathering, fungi, and salt damage.

- Experimental coating on Boso stone and part of the exterior wall at Nokogiriyama Museum
Experiment site: Nokogiriyama Museum Foundation*1 -

Experimental coating content: On November 18, 2022, Silicagen Coat - for antifouling and antibacterial use - was applied to parts of the Boso stone and exposed concrete parts of the exterior wall of the Nokogiriyama Museum, which appeared to be deteriorating, and the progress is being observed.

* Coating on Boso stone*2

Arrow

It seems that the lichens attached to the Boso stone are decreasing. Also, it seems that the dirt and deterioration of the stone itself are being prevented. We will continue to monitor the progress and verify the effects.

* Application to part of the exterior concrete

Arrow

The actual coated part is suppressing surface deterioration regardless of wind, rain, salt damage, or exhaust gas from the roadside. We will continue to monitor the progress and verify the effects.

[Impressions of Director Suzuki of Nokogiriyama Museum]
I am pleased that the lichens attached to the Boso stone coated with Silicagen Coat are gradually regressing. Also, I feel that the concrete coated with Silicagen Coat is less deteriorated compared to other parts.

*1: About Nokogiriyama Museum: Opened in March 2010 as Kanaya Museum.
As a symbol of "art" in Kanaya, Futtsu City, Chiba Prefecture, which is working on town revitalization with the theme of "stone and art," it has been familiar to local residents and tourists until now. In 2020, the name was changed to "Nokogiriyama Museum," named after the famous mountain in Chiba Prefecture, Nokogiriyama. Since then, it has been active as a museum promoting regional revitalization, education, and contribution to the local community through art and culture. It regularly holds the Nokogiriyama Competition, cultural exchange exhibitions with Switzerland and Sweden, and exhibitions of artists active at the forefront of the Japanese art world. Located 1 minute on foot from Tokyo Bay Ferry Kanaya Port, 5 minutes on foot from JR Uchibo Line Hamakanaya Station, and 3 minutes by car from Tateyama Expressway Futtsu Kanaya Interchange.
https://nokogiriyama.com/
*2: About Boso stone: A general term for tuffaceous sandstone or volcanic breccia tuff quarried from Nokogiriyama and its surroundings in the central and southern part of the Boso Peninsula. The one applied this time was taken from Nokogiriyama.

◇ Successfully Antiviralizing Mask Nonwoven Fabric Filters Using Choetsu Technology®

Research Group of Professor Kazuhito Satomura, Department of Oral Medicine, School of Dentistry, Tsurumi University

By applying silica resin coating technology (Choetsu Technology®) developed by Choetsu Kaken Co., Ltd., we succeeded in effectively antiviralizing nonwoven fabric filters inside surgical masks widely used in medical settings. The research group of Professor Kazuhito Satomura, Department of Oral Medicine, School of Dentistry, Tsurumi University, succeeded in effectively carrying antibacterial substances on the fiber surface of surgical mask nonwoven fabric filters by combining Choetsu Technology® with various antibacterial agents, and reported that inactivation effects of 99.999% or more against human coronavirus could be imparted to the nonwoven fabric using any of the antibacterial agents tested. This makes it possible to easily antibacterialize and antiviralize existing masks by applying Choetsu Technology®. Furthermore, the paper mentions the possibility of easily carrying various functional substances on the surface of various materials using Choetsu Technology®.
The details of this research result were published in the electronic version of the International Journal of Environmental Research and Public Health on March 22, 2022 (https://doi.org/10.3390/ijerph19063639).

Details herepdf